کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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4443032 | 1311175 | 2007 | 14 صفحه PDF | دانلود رایگان |
The bimolecular rate constants, kOH+β-ionone (118±30)×10−12 cm3 molecule−1 s−1 and kO3+β‐iononekO3+β‐ionone, (0.19±0.05)×10−16 cm3 molecule−1 s−1, were measured using the relative rate technique for the reaction of the hydroxyl radical (OH) and ozone (O3) with 4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one (β-ionone) at 297±3 K and 1 atm total pressure. To more clearly define part of β-ionone's indoor environment degradation mechanism, the products of the β-ionone+OH and β-ionone+O3 reactions were also investigated. The identified β-ionone+OH reaction products were: glyoxal (ethanedial, HC(=O)C(=O)H), and methylglyoxal (2-oxopropanal, CH3C(=O)C(=O)H) and the identified β-ionone+O3 reaction product was 2-oxopropanal. The derivatizing agents O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) and N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA) were used to propose 2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde as the other major β-ionone+OH and β-ionone+O3 reaction product. The elucidation of this other reaction product was facilitated by mass spectrometry of the derivatized reaction products coupled with plausible β-ionone+OH and β-ionone+O3 reaction mechanisms based on previously published volatile organic compound+OH and volatile organic compound+O3 gas-phase reaction mechanisms. The additional gas-phase products observed from the β-ionone+OH reaction are proposed to be the result of cyclization through a radical intermediate.
Journal: Atmospheric Environment - Volume 41, Issue 38, December 2007, Pages 8758–8771