کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4443646 | 1311203 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetics of the reaction between OH radicals and monochlorodimethylsulphide (CH3SCH2Cl)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
علم هواشناسی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Kinetics of the reaction between OH radicals and monochlorodimethylsulphide (CH3SCH2Cl) Kinetics of the reaction between OH radicals and monochlorodimethylsulphide (CH3SCH2Cl)](/preview/png/4443646.png)
چکیده انگلیسی
The gas-phase rate coefficient for the reaction between OH radicals and CH3SCH2Cl (MCDMS) was determined to be (2.5±1.3)×10−12 cm3 molecule−1 s−1 using the discharge–flow kinetic technique. An estimate of ≈10−10 cm3 molecule−1 s−1 was obtained for the rate coefficient for reaction of Cl with MCDMS.It would appear that the reaction with OH is not the main loss process for CH3SCH2Cl in the marine boundary layer. The possible implications for the MBL of halogen-promoted oxidation of dimethylsulphide are considered.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Atmospheric Environment - Volume 40, Issue 36, November 2006, Pages 6899–6904
Journal: Atmospheric Environment - Volume 40, Issue 36, November 2006, Pages 6899–6904
نویسندگان
Dudley E. Shallcross, Stewart Vaughan, David R. Trease, Carlos E. Canosa-Mas, Mariana V. Ghosh, John M. Dyke, Richard P. Wayne,