Annual variation of particulate organic compounds in PM2.5 in the urban atmosphere of Beijing

Beijing, the capital of China, is a rapidly developing mega-city with a huge population in the world. Beijing has been experiencing severe air pollution problems since 1980s due to more and more energy consumption. In the case of severe organic aerosol pollution in Beijing, a one-year-long observation on major organic compounds in PM2.5 was performed at an urban site to gain information of their ambient concentration levels and sources in Beijing. The compound classes identified by GC/MS included alkanes, PAHs, fatty acids, dicarboxylic acids, and hopanes, whose seasonal average concentrations during the year were 39–477, 9–283, 260–483, 16–42, and 2.3–16 ng m−3, respectively. Since the molecular distributions of particulate organic matter are indicative of different emission sources, their seasonal characteristics and variations were discussed in detail to explore the major contributing sources in Beijing. Conclusively, organic aerosol pollution in Beijing was found to be mostly associated with vehicle exhaust, coal combustion for residential heating, and cooking emissions, and the latter two sources are unique Chinese pollution sources. The dataset in this paper provides useful information for establishing effective control measures to reduce organic aerosol pollution in Beijing.