کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
44609 46044 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Formation of cyclopentanone from dimethyl hexanedioate over CeO2
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Formation of cyclopentanone from dimethyl hexanedioate over CeO2
چکیده انگلیسی

Cycloketonization of dimethyl hexanedioate into cyclopentanone was investigated over pure CeO2 at a temperature between 350 and 475 °C. The conversion of the diester increased with raising the reaction temperature. The selectivity to cyclopentanone, however, decreased whenever the conversion increased. The major by-product other than methanol was 2-methylcyclopentanone. It was found that methylation of cyclopentanone with methanol into 2-methylcyclopentanone proceeded over CeO2. The decrease in the selectivity to cyclopentanone at high conversion was mainly caused by a consecutive reaction of cyclopentanone into 2-methylcyclopentanone due to alkylation with methanol.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 312, 8 September 2006, Pages 175–180
نویسندگان
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