کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
44609 | 46044 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Formation of cyclopentanone from dimethyl hexanedioate over CeO2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
Cycloketonization of dimethyl hexanedioate into cyclopentanone was investigated over pure CeO2 at a temperature between 350 and 475 °C. The conversion of the diester increased with raising the reaction temperature. The selectivity to cyclopentanone, however, decreased whenever the conversion increased. The major by-product other than methanol was 2-methylcyclopentanone. It was found that methylation of cyclopentanone with methanol into 2-methylcyclopentanone proceeded over CeO2. The decrease in the selectivity to cyclopentanone at high conversion was mainly caused by a consecutive reaction of cyclopentanone into 2-methylcyclopentanone due to alkylation with methanol.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 312, 8 September 2006, Pages 175–180
Journal: Applied Catalysis A: General - Volume 312, 8 September 2006, Pages 175–180
نویسندگان
Osamu Nagashima, Satoshi Sato, Ryoji Takahashi, Toshiaki Sodesawa, Tetsu Akashi,