کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
44692 46056 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Selective thermomorphic biphasic hydroformylation of higher olefins catalyzed by HRhCO(PPh3)3/P(OPh)3
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Selective thermomorphic biphasic hydroformylation of higher olefins catalyzed by HRhCO(PPh3)3/P(OPh)3
چکیده انگلیسی

A thermomorphic approach to rhodium-catalyzed biphasic hydroformylation of higher olefins (C > 6) has been developed based on HRhCO(PPh3)3/P(OPh)3/propylene carbonate/n-heptane catalytic system. The catalyst system showed excellent selectivity toward the desired linear aldehyde (n/i ratio > 8) and high catalytic activity demonstrated by the efficient recycling without significant loss of the catalyst activity. The effects of the temperature, the total pressure, the ratio of CO/H2, the reaction time and the type of ligand have been thoroughly studied.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 303, Issue 2, 28 April 2006, Pages 158–165
نویسندگان
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