کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4547632 | 1627136 | 2006 | 18 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dissolution kinetics of high explosives particles in a saturated sandy soil
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
فرآیندهای سطح زمین
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Dissolution kinetics of high explosives particles in a saturated sandy soil Dissolution kinetics of high explosives particles in a saturated sandy soil](/preview/png/4547632.png)
چکیده انگلیسی
Solid phase high explosive (HE) residues from munitions detonation may be a persistent source of soil and groundwater contamination at military training ranges. Saturated soil column tests were conducted to observe the dissolution behavior of individual components (RDX, HMX, and TNT) from two HE formulations (Comp B and C4). HE particles dissolved readily, with higher velocities yielding higher dissolution rates, higher mass transfer coefficients, and lower effluent concentrations. Effluent concentrations were below solubility limits for all components at superficial velocities of 10-50 cm dayâ 1. Under continuous flow at 50 cm dayâ 1, RDX dissolution rates from Comp B and C4 were 34.6 and 97.6 μg hâ 1 cmâ 2 (based on initial RDX surface area), respectively, significantly lower than previously reported dissolution rates. Cycling between flow and no-flow conditions had a small effect on the dissolution rates and effluent concentrations; however, TNT dissolution from Comp B was enhanced under intermittent-flow conditions. A model that includes advection, dispersion, and film transfer resistance was developed to estimate the steady-state effluent concentrations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Contaminant Hydrology - Volume 85, Issues 3â4, 30 May 2006, Pages 141-158
Journal: Journal of Contaminant Hydrology - Volume 85, Issues 3â4, 30 May 2006, Pages 141-158
نویسندگان
Matthew C. Morley, Hiroshi Yamamoto, Gerald E. Jr., Jay Clausen,