کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4763030 | 1422955 | 2017 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Catalytic developments in the direct dimethyl carbonate synthesis from carbon dioxide and methanol
ترجمه فارسی عنوان
تحولات کاتالیستی در سنتز دی متیل کربنات مستقیم از دی اکسید کربن و متانول
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کلمات کلیدی
دی اکسید کربن، کربنات آلی، دی متیل کربنات، کاتالیزورها، عوامل کم آبی،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
The present review compiles the recently published literature for the single step dimethyl carbonate (DMC) synthesis from carbon dioxide (CO2) and methanol. The various routes of DMC synthesis are also discussed in short with their advantages and disadvantages in order to distinguish the merits of direct DMC synthesis route. Next, the major applications of DMC such as in electrochemistry, as fuels additive, as solvent and building block in organic synthesis are described. The major problems in the direct DMC synthesis route such as low yield, reaction rate, thermodynamic limitations and hydrolysis of produced DMC are also pointed out. Furthermore, the significance of fabricating an effective dehydrating agent for the removal of water from the reaction is narrated for the enhancement of DMC yield. The type of catalyst materials based on their nature i.e. metal carbonates, tin-based catalysts, metal oxides, organic catalysts and polymer based materials, etc. used for title reaction are separately discussed in details. The varieties of dehydrating agents and their role in DMC production is explained with the help of most recent reported literature.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 323, 1 September 2017, Pages 530-544
Journal: Chemical Engineering Journal - Volume 323, 1 September 2017, Pages 530-544
نویسندگان
Ashif H. Tamboli, Avinash A. Chaugule, Hern Kim,