کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4767932 1424514 2017 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Application of 1-hexyl-3-methylimidazolium trifluoromethanesulfonate to the removal of alcohol from mixtures with heptane
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Application of 1-hexyl-3-methylimidazolium trifluoromethanesulfonate to the removal of alcohol from mixtures with heptane
چکیده انگلیسی
An ionic liquid (IL) of 1-Hexyl-3-methylimidazolium trifluoromethanesulfonate [Hmim][OTf] was investigated as a possible extraction solvent in petrochemical processes for the removal of alcohol from an azeotropic mixture with heptane. Liquid-liquid equilibrium (LLE) experiments of three ternary systems, hexane + ethanol, 1-propanol, or 2-propanol + [Hmim][OTf], were conducted at 298.15 K and atmospheric pressure. The efficiency of [Hmim][OTf] as an extraction solvent was determined by calculating the solute distribution ratio, β, and selectivity, S, and this efficiency was compared to other ionic liquids from the literature. The structural volume (r) and surface area (q) of [Hmim][OTf] were determined using a quantum chemistry approach. The LLE data of the three ternary systems were correlated using NRTL and UNIQUAC models, and the UNIFAC model was used to predict the phase behavior compared to the experimental data.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 443, 15 July 2017, Pages 44-49
نویسندگان
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