کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4768120 | 1424527 | 2016 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Determination of solubility parameters from density measurements for non-polar hydrocarbons at temperatures from (298-433) K and pressures up to 137Â MPa
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The Hildebrand's solubility parameter, δ, gives a quantitative representation of the well-known “like dissolves like” aphorism for non-polar hydrocarbon liquids. This is of great commercial importance for certain polymers and hydrocarbon mixtures. However, the solubility parameters are usually available only at ambient conditions for a limited number of substances. Extrapolation of these parameters to high pressure and high temperature conditions is not attained by common empirical correlations or cubic equations of state. In this work a set of equations are derived from fundamental thermodynamic property relations to account for the pressure and temperature dependence of this cohesive energy parameter. The equations, which require a reference value for the solubility parameter -usually at ambient conditions- and volumetric data, are then applied to calculate the solubility parameters of four pure non-polar hydrocarbons, namely n-heptane, n-dodecane, benzene and toluene, at temperatures from (298-433) K and pressures up to 137 MPa. A comparison against literature data and predictions from the Perturbed Chain version of the Statistical Association Fluid Theory (PC-SAFT) and Peng-Robinson equations of state is also provided. The proposed method provides a novel approach for a quick, simple and accurate determination of the solubility parameters at elevated temperatures and pressures for non-polar hydrocarbons using density measurements.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 430, 25 December 2016, Pages 19-32
Journal: Fluid Phase Equilibria - Volume 430, 25 December 2016, Pages 19-32
نویسندگان
Fei Wang, Timothy J. Threatt, Francisco M. Vargas,