کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4908137 | 1426594 | 2016 | 5 صفحه PDF | دانلود رایگان |
- Immobilization of tetrazine by formation inclusion complexes with β-cyclodextrin
- Immobilized tetrazines keep their electrochemical and emission properties.
- New supramolecular fluorescent poly(pyrrole β-cyclodextrin) - tetrazine films
- Fast and easy binding of different tetrazine derivatives on electrode surfaces
- A tetrazine-naphthalimide derivative used as a bridge between polymer and enzyme
Tetrazines were immobilized onto electrogenerated films of polypyrrole functionalized with β-cyclodextrin. Their immobilization was ascribed to the formation of the inclusion complexes between the tetrazines derivatives and the β-cyclodextrin cavity. We proved that the resulting supramolecular material kept the electrochemical and fluorescent properties of tetrazines. This original architecture was used with success as a “bridge” to immobilize the β-cyclodextrin-tagged glucose oxidase, chosen as an enzyme model, to prove the efficiency of the method to build new supra-biomolecular architectures.
Journal: Journal of Electroanalytical Chemistry - Volume 781, 15 November 2016, Pages 36-40