کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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4908190 | 1426594 | 2016 | 6 صفحه PDF | دانلود رایگان |
In this work, we successfully prepared well-defined bimetallic alloyed Pt-Pd nanocubes (NCs) supported on reduced graphene oxide nanosheets (rGO-Pt-Pd NCs). Pt-Pd NCs were uniformly dispersed on rGO by hydrothermal treatment of preformed Pt-Pd NCs and GO in alkaline media. The detailed morphology, crystal structure and composition were well characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Furthermore, with the special structure of Pt-Pd NCs and the synergetic effects of Pt, Pd and rGO, the rGO-Pt-Pd NCs modified electrode exhibited excellent electrocatalytic performance in the sensing of chloramphenicol (CAP). The linear covered the range of 0.2-30 μM and the detection limit reached 0.1 μM (S/N = 3). The modified electrode also displayed good stability, high reproducibility and satisfactory selectivity.
Journal: Journal of Electroanalytical Chemistry - Volume 781, 15 November 2016, Pages 389-394