کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
49599 | 46756 | 2014 | 4 صفحه PDF | دانلود رایگان |

• Synthesis of a palladium complex with a nitrogen-containing bis(phosphinite)
• The ligand is bound to palladium in a P,P-bidentate coordination mode.
• The bite angle P–Pd–P is 98.90°.
• Efficient Suzuki–Miyaura coupling of aryl bromides at room temperature
• Activated aryl bromides displayed high yields for biaryls even within minutes.
A palladium(II) complex with a known inexpensive and very easily synthesized nitrogen-containing bis(phosphinite) ligand has been prepared and characterized by spectroscopic and crystallographic studies. The ligand is bound to the metal in a P,P-bidentate coordination mode with a bite angle of 98.90°. This complex was found to be an efficient catalyst for room-temperature Suzuki–Miyaura coupling of a variety of aryl bromides with phenylboronic acid. At 0.1 mol% of palladium in DMF/K3PO4 for 24 h, the corresponding biaryls were obtained with 75–92% yields. Activated substrates displayed high yields even within minutes.
Figure optionsDownload as PowerPoint slide
Journal: Catalysis Communications - Volume 51, 5 June 2014, Pages 15–18