کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4979208 1453023 2017 31 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Experimental study on the thermal decomposition and combustion characteristics of nitrocellulose with different alcohol humectants
ترجمه فارسی عنوان
بررسی تجربی بر روی تجزیه حرارتی و ویژگی های احتراق نیتروسلولز با اشباع کننده های مختلف الکل
کلمات کلیدی
نیترو سلولوز، نرخ آزاد شدن حرارت، کمپرسور الکل رفتار احتراق بی ثباتی حرارتی،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
چکیده انگلیسی
Although the thermal behaviors including thermal instability of nitrocellulose (NC) and its mixtures with some humectants have been comprehensively examined previously in the literature, their combustion characteristics have not been systematically studied. To address the issue, the combustion properties of NC with alcohol humectants are investigated by the means of the ISO 5660 cone calorimeter. Two kinds of NC-humectant mixtures with 30 wt.% isopropanol and 30 wt.% ethanol, respectively, were employed as samples. The tests were conducted under different external radiations, ranging from 0-15 kW/m2. The experimental results indicate that the external radiation positively influences the peak heat release rate (HRR) intensity and the maximum mass loss rate (MLR), while the total heat release (THR) decreases with the elevated external radiation. Comparatively, the sample with isopropanol exhibits a higher fire risk, characterized by the higher peak HRR, THR and maximum MLR. Auxiliary investigating methods, including Scanning Electron Microscopy and Differential Scanning Calorimeter-Thermal Gravimetric Analysis, were applied to examine the micro structure and thermal behavior of NC-humectant mixtures. The results helped to explain the burning characteristics observed in the cone calorimeter tests.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 340, 15 October 2017, Pages 202-212
نویسندگان
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