An efficient hydration of nitriles to amides in aqueous media by hydrotalcite-clay supported nickel nanoparticles

Hydrotalcite-clay supported nickel nanoparticles catalyze hydration of nitriles to amides in aqueous media. This Ni NPs/HT system is efficient for the synthesis of a diverse range of amides and affords the expected products with good yields in aqueous media. The synthesized nickel nanoparticles are characterized by UV-DRS, powder XRD, SEM and HRTEM. The catalyst is reused at least three times and a plausible mechanism is proposed. This fast, simple, effective and environmentally benign heterogeneous protocol provides a safer alternative to hazardous, corrosive and more polluting conventional catalysts.

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► First report on synthesis of hydrotalcite supported Ni nanoparticles.
► Ni NPs/HT as heterogeneous catalyst for green and reusable method for hydration of nitriles to amides in water.
► The catalyst is reused three times and suitable mechanism is proposed.