کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4987081 | 1455144 | 2017 | 49 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Formulation optimization of reverse microemulsions using design of experiments for nanoparticles synthesis
ترجمه فارسی عنوان
بهینهسازی فرمولبندی میکرومولسیونهای معکوس با استفاده از طراحی آزمایشهای سنتز نانوذرات
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
چکیده انگلیسی
The present work investigates the development of water/mixed nonionic surfactant/co-surfactant/cyclohexane reverse microemulsions (RM) suitable for nanoparticles synthesis. The mixture of Span 80 (oil soluble) and Tween 80 (water soluble) was selected as the surfactants. Optimum formulation of RM was obtained by using the Box-Behnken (33) experimental design method to evaluate the effect of three independent process variables, i.e., pH, Span 80 wt% in surfactant mixture, and propyl alcohol wt% in mixture of cyclohexane and propyl alcohol, on the preferred responses: average droplet size (ADS) and polydispersity index (PDI) of droplets. The model was validated experimentally based on an ANOVA table, and was optimized to reach the optimum formulation to yield the ADS and PDI for RMs. The determination coefficient (R2) values of 0.991 for ADS and 0.975 for PDI show that Box-Behnken design is a useful platform for the optimization of RMs formulation. Finally, iron oxide nanoparticles were synthesized under the optimum RM conditions and the uniform nanoparticle distribution with an average particle size of 2.1 ± 0.49 nanometer and a polydispersity of 0.06 ± 0.011 were obtained.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Research and Design - Volume 125, September 2017, Pages 367-384
Journal: Chemical Engineering Research and Design - Volume 125, September 2017, Pages 367-384
نویسندگان
Ehsan Nourafkan, Hui Gao, Zhongliang Hu, Dongsheng Wen,