کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4987994 | 1455293 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of anion exchange membranes from BPPO and dimethylethanolamine for electrodialysis
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
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چکیده انگلیسی
In this research work, the synthesis of anion exchanges membranes (AEMs) from brominated poly (2, 6-dimethyl-1, 4-phenylene oxide) (BPPO) and dimethyethanolamine (DMEA) has been investigated for electrodialysis (ED) application. Fourier transform infrared spectroscopy was used to confirm the functional groups in the membranes. The morphology of the prepared membranes was investigated by scanning electron microscopy. Physiochemical and electrochemical properties of the prepared membranes were studied in detail. The membranes possess ion exchange capacity of 0.66Â mmol/g to 1.38Â mmol/g, water uptake of 11.60% to 48.50%, volume expansion ratio of 8.58% to 20.21%, tensile strength of 32.52Â MPa to 49.22Â MPa and transport number of 0.94 to 0.98. These membranes have higher chemical stability in alkaline medium than QPPO membrane (quaternized with trimethylamine) at room temperature. The membranes DMEA-10 and DMEA-15 were selected for NaCl desalination by ED with a lab-scale electrodialysis cell at constant applied voltage. The prepared membranes DMEA-10 and DMEA-15 showed better performance than the commercial anion exchange membranes Neosepta AMX under the identical conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Desalination - Volume 402, 16 January 2017, Pages 10-18
Journal: Desalination - Volume 402, 16 January 2017, Pages 10-18
نویسندگان
Muhammad Imran Khan, Chunlei Zheng, Abhishek N. Mondal, Md. Masem Hossain, Bin Wu, Kamana Emmanuel, Liang Wu, Tongwen Xu,