کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
49926 46773 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Octahedra-based molecular sieve aluminoborate (PKU-1) as solid acid for heterogeneously catalyzed Strecker reaction
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Octahedra-based molecular sieve aluminoborate (PKU-1) as solid acid for heterogeneously catalyzed Strecker reaction
چکیده انگلیسی


• Heterogeneously catalyzed Strecker reaction between imine and TMSCN
• Octahedral framework molecular sieve (PKU-1) used as solid acid catalyst
• Specific Lewis and Brønsted acid sites provided in the backbone of aluminoborate (PKU-1)
• Borates hydroxyl groups act as critical active centers.

An aluminoborate (PKU-1) with octahedron-based framework was found to be a highly efficient solid acid catalyst for the rapid and convenient synthesis of α-aminonitriles from imines and TMSCN under mild reaction conditions. The catalytic active sites are related to the borate hydroxyl groups in the 18-ring structural channels. The borate hydroxyl groups play a critical role as Brønsted acid to protonate imine and activate TMSCN, thus providing the imine intermediate and producing CN anions, respectively.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 58, 5 January 2015, Pages 174–178
نویسندگان
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