DABCO tribromide immobilized on magnetic nanoparticle as a recyclable catalyst for the chemoselective oxidation of sulfide using H2O2 under metal- and solvent-free conditions

• MNPs-DABCO tribromide as a source of bromine was synthesized and characterized.
• MNPs-DABCO tribromide-catalyzed efficient the chemoselective oxidation of sulfides.
• H2O2 was used as a green, commercially available and chemically stable oxidant.
• The catalyst was easily reused without any significant loss in catalytic activity.

Magnetic nanoparticle-supported 1,4-diazabicyclo[2.2.2] octane tribromide (MNPs-DABCO tribromide) as a bromine source was readily prepared and characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and vibrating sample magnetometry (VSM) techniques. The catalytic activity of MNPs-DABCO tribromide was investigated in the chemoselective oxidation of sulfides to sulfoxides using 30% H2O2 as an oxidant at room temperature under solvent-free conditions. The heterogeneous catalyst could be recovered easily and reused 15 times without significant loss of its catalytic activity.

DABCO tribromide immobilized on magnetic nanoparticle as a recyclable catalyst for the chemoselective oxidation of sulfide using H2O2 under metal- and solvent-free conditions.Figure optionsDownload as PowerPoint slide