کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
50612 | 46804 | 2012 | 4 صفحه PDF | دانلود رایگان |

The Suzuki–Miyaura reaction has been performed using a phosphine-free perfluoro-tagged palladium catalyst that is readily immobilized on fluorous silica gel through fluorous–fluorous interactions (Pd-1/FSG). The reactions are carried out under aerobic and phosphine-free conditions with excellent to quantitative product yields, and very low palladium content (< 0.8 ppm) in the products was detected by ICP-AES. The catalyst can be recovered by simple filtration and reused several times without significant loss of activity.
The Suzuki–Miyaura reaction has been performed using a phosphine-free perfluoro-tagged nano-palladium catalyst that is readily immobilized on fluorous silica gel through fluorous–fluorous interactions. The immobilized fluorous nano-palladium catalyst can be recovered by simple filtration and reused several times without significant loss of activity.Figure optionsDownload as PowerPoint slideHighlights
► A novel perfluoro-tagged nano-palladium catalyst (Pd-1/FSG) has been prepared.
► All reactions went smoothly in methanol/water and high yields were obtained.
► Very low palladium content (< 0.8 ppm) in the products was detected by ICP-AES.
► The catalyst can be reused several times without significant loss of activity.
Journal: Catalysis Communications - Volume 24, 5 July 2012, Pages 105–108