کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
50921 | 46821 | 2013 | 5 صفحه PDF | دانلود رایگان |
• Novel α-ketoesters were conveniently synthesized from β-diketones via vanadium.
• These α-ketoesters could be prepared under additive-free, mild conditions using O2.
• DFT calculations were performed to provide insights into the tandem transformation.
Novel α-ketoesters were conveniently synthesized from acetylacetone and analogs via a vanadium-mediated one-pot tandem process. These advanced α-ketoesters could be selectively prepared under additive-free, mild conditions, viz., 1 atm O2 pressure and 50–80 °C. DFT calculations were performed to provide insights into the detailed mechanism of the tandem transformation.
Novel α-ketoesters were conveniently synthesized from β-diketones via a vanadium-mediated one-pot tandem process. These advanced α-ketoesters could be selectively prepared under additive-free, mild conditions, viz., 1 atm O2 pressure and 50–80 °C. DFT calculations were performed to provide insights into the detailed mechanism of the tandem transformation.Figure optionsDownload as PowerPoint slide
Journal: Catalysis Communications - Volume 37, 5 July 2013, Pages 109–113