کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
50997 46824 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
DRIFTS study of methanol adsorption on Mg–Al hydrotalcite catalysts for the transesterification of vegetable oils
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
DRIFTS study of methanol adsorption on Mg–Al hydrotalcite catalysts for the transesterification of vegetable oils
چکیده انگلیسی

Mg–Al hydrotalcites rehydrated after calcination are promising catalysts for the methanolysis of vegetable oils. To gain insight into the basis of their catalytic action, the adsorption of methanol over some commercial Mg–Al hydrotalcites was studied by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Different species formed after methanol adsorption were identified, being the total quantity of methoxy species related to the basic character of the sample. A linear correlation between the amount of adsorbed monodentate methoxy species and the catalytic activity in the biodiesel production was found. Therefore, it is proposed that these species are the mainly involved in the transesterification reaction.

Figure optionsDownload as PowerPoint slideHighlights
► A correlation was found between monodentate methoxy species and methanolysis activity.
► Monodentate methoxy species are involved in methanolysis over Mg–Al hydrotalcites.
► Bidentate methoxy species are strongly adsorbed and less labile than monodentate ones.
► As the Al content increases the likelihood of forming bidentate species is higher.
► Mg/Al ratio and hydration state are key for the hydrotalcites methanolysis activity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 17, 5 January 2012, Pages 189–193
نویسندگان
, , , , , ,