An EIS study of the conservation treatment of the bronze sphinxes at the Museo Arqueológico Nacional (Madrid)

During the restauration process of the bronze sphinxes at the main façade of the National Archaeological Museum in Madrid, collaboration with conservators has been established to test the performance of a recently developed gel-electrolyte cell for the electrochemical evaluation of metal cultural heritage. Electrochemical measurements (EIS and Rp) of the patinas have been carried out before, during and after the conservation treatments, on two different areas of the sculpture. This has provided information on how the protective coatings have improved corrosion resistance by 3 orders of magnitude, and how this protection is starting to decrease with time; periodic measurements will allow verifying the performance of the treatment over time and detecting the failure of the protection treatment before its effects are visible on the surface.