کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5133232 1492062 2017 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Bionic multi-tentacled ionic liquid-modified silica gel for adsorption and separation of polyphenols from green tea (Camellia sinensis) leaves
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Bionic multi-tentacled ionic liquid-modified silica gel for adsorption and separation of polyphenols from green tea (Camellia sinensis) leaves
چکیده انگلیسی


- Bionic multi-tentacled ionic liquid sorbent was prepared for the first time.
- It has excellent abilities of selective absorption as well as fine separation.
- Properties, performance and mechanism were investigated comprehensively.
- Bioactivity was also evaluated for the separation and had good result.

For the first time, a new kind of bionic multi-tentacled ionic liquid-modified silica gel was synthesized and used as selective adsorbent in the preparative separation of tea polyphenols (TP) from green tea leaves. It was found that silica particles with polyvinyl alcohol chains modified by N-methyl imidazole proline salt (PVA·Im+·Pro−@SiO2) had the excellent performance in selective adsorption as well as fine separation for target compounds. The new adsorbent exhibited high adsorption capacity and good reusability, meanwhile the antioxidant activity of TP could be improved through its efficient enrichment. It properties and adsorption mechanism were also investigated comprehensively and compared with those reported sorbents. Finally, the preparative separation of individual catechin from crude extracts was successfully achieved on the chromatographic column packed with PVA·Im+·Pro−@SiO2 particles and four main constituents were obtained successively. The study was expected to provide a new way for the effective separation of similar bioactive compounds.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Food Chemistry - Volume 230, 1 September 2017, Pages 637-648
نویسندگان
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