کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5136753 | 1494014 | 2017 | 6 صفحه PDF | دانلود رایگان |
- The second order focusing conditions have been found for the sector field TOF mass analyzer with orthogonal acceleration.
- The aberrational limit of RFW â 80,000 has been found for the δE/E0 = 2.5% at OA exit and 50 μs spectra duration for m/z 1000.
- It allows to achieve higher mass resolution with a high acquisition rate (up to 10-20Â kHz).
Original orthogonal acceleration (OA) electrostatic sector time of flight (TOF) mass analyzer is proposed those allows the second order focusing of time of flight by initial ions position. Resolving power aberration limit exceeding 80,000 FW (full width mass peak) was shown to be obtainable for mass analyzer with the total length of flight LÂ =Â 133.2Â cm, the average ion energy 3700Â V and the ion energy spread of 2.5% on the entrance of sector field.
Journal: Journal of Chromatography B - Volume 1047, 15 March 2017, Pages 39-44