کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5139270 1494863 2017 37 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Combination of dispersive solid phase extraction and dispersive liquid-liquid microextraction for extraction of some aryloxy pesticides prior to their determination by gas chromatography
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Combination of dispersive solid phase extraction and dispersive liquid-liquid microextraction for extraction of some aryloxy pesticides prior to their determination by gas chromatography
چکیده انگلیسی
In this study a new version of solid phase extraction performed in a narrow-bore tube using large volume of sample followed by dispersive liquid-liquid microextraction has been proposed to achieve a high sensitive analytical method. It has been used for the extraction and preconcentration of trace concentrations of some pesticides (metalaxyl, haloxyfop-r-methyl, clodinafop-propargyl, diclofop-methyl, and bromopropylate) in different vegetables (potato, tomato, onion, garlic, celery, radish, beet, and carrot) followed by gas chromatography-flame ionization detection. In the proposed method mg-level of a sorbent (C8) is mixed with a dispersive solvent (iso-propanol) and then dispersed into an aqueous solution placed into a narrow-bore tube. By this action, the sorbent passes through the solution in a short time instead of passing the solution from the cartridge in conventional solid phase extraction in a long time. To achieve high enrichment factors, an appropriate organic solvent (acetonitrile) is used to elute the compounds of interest from the sorbent for the following dispersive liquid-liquid microextraction procedure. Some important parameters which affect the extraction efficiency were studied. Under the optimum extraction conditions, the method showed wide linear ranges (0.08-10,000 μg L− 1). Enrichment factors and extraction recoveries were in the ranges of 1702-4147 and 31-75%, respectively. Detection limits were in the range of 0.02-0.25 μg L− 1 in solution (0.01-0.89 μg kg− 1 in samples). LOQs were obtained in the range of 0.08-0.83 μg L− 1 in solution (0.04-2.9 μg kg− 1 in samples). Relative standard deviations of 4-7% (n = 6) and 2-4% (n = 7) were obtained for 10 and 50 μg L− 1 of each analyte, respectively. The relative recoveries obtained in three different concentrations were 80-101%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 131, March 2017, Pages 182-191
نویسندگان
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