کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51410 | 46842 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The hydrophilic/hydrophobic effect of porous solid acid catalysts on mixed liquid phase reaction of esterification
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The hydrophilic/hydrophobic effect of porous solid acid catalysts on mixed liquid phase reaction of esterification The hydrophilic/hydrophobic effect of porous solid acid catalysts on mixed liquid phase reaction of esterification](/preview/png/51410.png)
چکیده انگلیسی
The esterification between n-butanol and acetic acid was catalyzed by SBA-15 with a heteropoly acid fixed in the channels, which was synthesized with different hydrophilic/hydrophobic property. In a rigorous sealed batch reactor, the conversions of the reactants surpassed the limit of chemical equilibrium with the hydrophilic catalyst, from which the hydrophobic n-butyl acetate would be rejected. The counter-reaction of hydrolysis was then suppressed. The concept demonstrated in the current work sheds light on the design of practical catalysts and reactors free of complicated separation processes for a reaction in oil/water mixing phase.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 13, 25 July 2009, Pages 1734–1737
Journal: Catalysis Communications - Volume 10, Issue 13, 25 July 2009, Pages 1734–1737
نویسندگان
Hong Liu, Nianhua Xue, Luming Peng, Xuefeng Guo, Weiping Ding, Yi Chen,