کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5145285 | 1497341 | 2017 | 8 صفحه PDF | دانلود رایگان |
- Ti2Nb10O29 (TNO) microspheres were prepared combining a solvothermal method with a subsequent heat-treatment.
- TNO microspheres used Ti(OC3H7)4 and NbCl5 as starting materials.
- TNO microspheres show excellent electrochemical properties at high current densities.
Ti2Nb10O29 (TNO) microspheres are fabricated combining a solvothermal method with a subsequent heat-treatment. Structural and morphological properties of the as-prepared material have been characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption/desorption. The electrochemical performance is evaluated by performing cyclic voltammograms and galvanostatic discharge/charge tests. The electrochemical characterization demonstrates that the as-prepared TNO microspheres exhibit a good electrochemical performance with a discharge capacity of 185 mAh gâ1 after 200 cycles and a capacity retention of 94% at 10 C. Furthermore, since TNO may react with Li at a voltage above 1.0 V vs. Li+/Li, TNO microspheres could be the promising high-power anode materials for 2 V vs. Li+/Li lithium-ion batteries applications.
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 36, 7 September 2017, Pages 22965-22972