کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5145752 | 1497361 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen storage properties of 2Mg-Fe mixtures processed by hot extrusion at different temperatures
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Hydrogen storage properties of 2Mg-Fe mixtures processed by hot extrusion at different temperatures Hydrogen storage properties of 2Mg-Fe mixtures processed by hot extrusion at different temperatures](/preview/png/5145752.png)
چکیده انگلیسی
2Mg-Fe mixtures produced by high-energy ball milling were consolidated into bulk form by hot extrusion at different processing temperatures (573 K (300 °C), 623 K (350 °C) and 673 K (400 °C)), aiming to evaluate their influence on the structure and microstructure of bulk materials and their consequent influence on the hydrogen sorption properties. In spite being in the nanosize range, the highest the processing temperature, the larger the grain sizes. However, the nanometric grain size remained after any hot extrusion condition, as estimated by Rietveld refinement. The pinning effect of Fe on Mg grain boundaries explained this effect. In the first absorption (activation), powders showed a hydrogen storage capacity of â¼4.53 wt%, while the extruded samples (bulk materials) reached almost the same capacity during the period of hydrogenation (â¼94% of the maximum hydrogen storage capacity for Mg2FeH6 - 5.5 wt%). The smallest crystallite sizes and highest surface area for hydrogenation explain the good performance of powders. However, when comparing only extruded samples, it was observed that the highest capacity and the lowest incubation times were mainly related to grain sizes and to the favorable texture along (002) plane of αMg. The desorption temperature of bulk materials was very similar to that of powders, which is good considering the lower surface area of bulk materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 16, 20 April 2017, Pages 11493-11500
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 16, 20 April 2017, Pages 11493-11500
نویسندگان
G.F. de Lima Andreani, M.M. Miglioli, M.R.M. Triques, V. Roche, C.S. Kiminami, W.J. Botta, A.M. Jr.,