کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5145821 | 1497377 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical catalysis investigation into the dynamic coordination properties of a pyridine-substituted [2Fe2S] model complex
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electrochemical catalysis investigation into the dynamic coordination properties of a pyridine-substituted [2Fe2S] model complex Electrochemical catalysis investigation into the dynamic coordination properties of a pyridine-substituted [2Fe2S] model complex](/preview/png/5145821.png)
چکیده انگلیسی
A pyridine substituted [2Fe2S] model complex 1 was fully characterized by spectroscopic methods and single-crystal structure analysis. The investigation of complex 1 has demonstrated that a reversible transformation reaction between the complex 1 and (μ-dmedt)Fe2(CO)5(NCCH3), which could mimic the function of the flexible coordination site in the hydrogenases. Electrochemical studies showed complex 1 has the ability to catalyze hydrogen evolution from HOAc and aqueous media at â1.26 V.285
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 48, 28 December 2016, Pages 22991-22996
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 48, 28 December 2016, Pages 22991-22996
نویسندگان
Xia Zhang, Tianyong Zhang, Yanhong Wang, Bin Li, Guanghui Zhang, Li Hai, Shuang Jiang,