کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5145925 | 1497343 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pt nanoparticles modified Au dendritic nanostructures: Facile synthesis and enhanced electrocatalytic performance for methanol oxidation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Pt nanoparticles modified Au dendritic nanostructures: Facile synthesis and enhanced electrocatalytic performance for methanol oxidation Pt nanoparticles modified Au dendritic nanostructures: Facile synthesis and enhanced electrocatalytic performance for methanol oxidation](/preview/png/5145925.png)
چکیده انگلیسی
A facile and simple method is presented for the synthesis of bimetallic composites, Pt nanoparticles modified dendritic Au nanostructures (PtNPs/DGNs), in which dendritic Au was deposited on a glassy carbon electrode via a potentiostatic method and sphere-like Pt nanoparticles were decorated on Au substrates through a chemical reduction reaction. The compositions, morphologies, and structures of the PtNPs/DGNs were characterized by X-ray photoelectron spectroscopy, field emission scanning electron microscopy, and energy dispersive X-ray spectroscopy. Results indicated that bimetallic composites were successfully synthesized and spherical Pt nanoparticles were dispersed evenly on dendritic Au substrates. The number of Pt nanoparticles on Au surface was regulated by controlling the chemical reduction deposition time, allowing the electrocatalytic properties of the composite towards methanol oxidation to be tuned. Electrochemical measurements, including cyclic voltammetry and chronoamperometry, were performed to investigate the electrochemical properties and electrocatalytic behaviors of the PtNPs/DGNs towards methanol oxidation. Pt nanoparticles partially covered dendritic Au exhibited dramatically enhanced electrocatalytic activity (3.947Â mAÂ cmâ2), which was 2.65 times that of commercial carbon-supported Pt nanoparticles (1.487Â mAÂ cmâ2), along with much improved poisoning tolerance (current decline: 70.85% vs 99.36%). These enhanced performances were likely caused by the large active electrochemical area of the bimetallic nanocomposites and the change in the electronic structure of Pt when the Au surface was modified with fewer Pt nanoparticles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 34, 24 August 2017, Pages 22100-22107
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 34, 24 August 2017, Pages 22100-22107
نویسندگان
Hongmei Jia, Gang Chang, Honghui Shu, Maji Xu, Xunying Wang, Zaoli Zhang, Xiong Liu, Hanping He, Kai Wang, Ruizhi Zhu, Yunbin He,