کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5145943 | 1497343 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chemical stability and electrical and mechanical properties of BaZrxCe0.8-xY0.2O3 with CeO2 protection method
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Chemical stability and electrical and mechanical properties of BaZrxCe0.8-xY0.2O3 with CeO2 protection method Chemical stability and electrical and mechanical properties of BaZrxCe0.8-xY0.2O3 with CeO2 protection method](/preview/png/5145943.png)
چکیده انگلیسی
This study investigated the decline in the conductivity and mechanical strength after CO2 poisoning and found a new protective method for BaZrxCe0.8-xY0.2O3 proton-conducting electrolyte. The high temperature solid state reaction (SSR) was used in synthesizing electrolyte to naturally generate CeO2 on the surface. A comparison of the oxides in the conductivity decline test revealed that the sample with CeO2 on the surface substantially improved the stability of conductivity, reducing the decline ratio from 56% to 7% for BCY electrolyte and 50% to 7% for BCZY sample. Raman mapping results indicate the naturally generated CeO2 on electrolyte surface can considerably reduce impurity formation and maintain the microstructure of electrolyte. This work demonstrates that samples with CeO2 on the surface effectively protect the BaCeO3-based proton-conducting electrolyte from CO2 poisoning. This method may be applied to similar BaCeO3-based perovskite materials as a new protective method.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 34, 24 August 2017, Pages 22259-22265
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 34, 24 August 2017, Pages 22259-22265
نویسندگان
Jhe-Wei Jhuang, Kan-Rong Lee, Jeng-kuei Chang, Chin-Tien Shen, Yi-Hsuan Lee, Sheng-Wei Lee, Chung-Jen Tseng,