کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5146005 | 1497344 | 2017 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterization and performance evaluation of PtRu/CTiO2 anode electrocatalyst for DMFC applications
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Characterization and performance evaluation of PtRu/CTiO2 anode electrocatalyst for DMFC applications Characterization and performance evaluation of PtRu/CTiO2 anode electrocatalyst for DMFC applications](/preview/png/5146005.png)
چکیده انگلیسی
In this study, the effect of introduction of titania (TiO2) material into PtRu/C anode electrocatalyst on the performance of direct methanol fuel cells (DMFCs) was investigated. TiO2 materials were first synthesized applying a sol-gel method and then incorporated directly into commercial PtRu/C anode electrocatalyst with different TiO2 weight ratios (5, 15, and 25 wt.%) to improve the performance of the DMFC. For comparison, the anode electrocatalysts with the same TiO2 weight ratios were also prepared using commercial TiO2 materials. The performance tests of the DMFCs based on these composite anode electrocatalysts were conducted and their performances were also compared to that of a DMFC based on a traditional anode electrocatalyst (PtRu/C) under various operating conditions. In addition, 4 h short-term stability tests were conducted for all the manufactured DMFCs. The highest power densities were found as 705.12 W/m2 and 709.32 W/m2 at 80 °C and 1 M for the DMFCs based on PtRu/CTiO2 anode electrocatalysts containing 5 wt.% of commercial and in-house TiO2, respectively. The results of the short-term stability tests showed that introduction of 5 wt.% of commercial TiO2 into commercial PtRu/C anode electrocatalyst improved its stability characteristics significantly.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 33, 17 August 2017, Pages 21518-21529
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 33, 17 August 2017, Pages 21518-21529
نویسندگان
Mustafa Ercelik, Adnan Ozden, Erol Seker, C. Ozgur Colpan,