کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5146211 | 1497348 | 2017 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen storage thermodynamics and kinetics of RE-Mg-Ni-based alloys prepared by mechanical milling
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The nanocrystalline/amorphous NdMg11Ni + x wt.% Ni (x = 100, 200) composite hydrogen storage alloys were synthesized by ball milling, and the effects of Ni content and milling time on the hydrogen storage thermodynamics and dynamics of the alloys were systematically investigated. The results reveal that the variation of the Ni content has a slight effect on the thermodynamic properties of the alloys, but it significantly improves their absorption and desorption kinetics performance. The variation of the milling time clearly affects the hydrogen storage properties of the alloys. Hydrogen absorption capacity and hydrogen absorption saturation ratio have maximum values with milling time varying. But hydrogen desorption ratio always increases with milling time prolonging. It is found that the hydrogen desorption activation energy of the alloys clearly decreases with increasing Ni content and milling time, which is responsible for the improved hydrogen desorption kinetics of the alloys.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 29, 20 July 2017, Pages 18473-18483
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 29, 20 July 2017, Pages 18473-18483
نویسندگان
Yan Qi, Yanghuan Zhang, Wei Zhang, Jinliang Gao, Zeming Yuan, Wengang Bu, Yaqin Li, Shihai Guo,