کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5146276 | 1497345 | 2017 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Methanol tolerant core-shell RuFeSe@Pt/C catalyst for oxygen reduction reaction
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Pt decorated RuFeSe/C catalyst is prepared by reduction of Pt precursor on pre-formed RuFeSe/C for oxygen reduction reaction (ORR). The catalyst is characterized by X-ray diffraction (XRD), energy dispersive spectrometer (EDS), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The catalyst particles are found to disperse on the carbon support with an average particle size of 2.8Â nm. Physical characterizations and electrochemical tests confirm that Pt is deposited on the surfaces of RuFeSe particles and RuFeSe@Pt/C catalyst has a core-shell structure. The as-prepared catalyst has high durability and shows high ORR activity through a four-electron transfer process. RuFeSe@Pt/C exhibits 1.3-fold greater specific activity and 1.4-fold greater mass activity for ORR than Pt/C. More importantly, it has excellent tolerance to methanol. Consequently, RuFeSe@Pt/C may be used as fine cathode catalyst in direct methanol fuel cells (DMFCs).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 32, 10 August 2017, Pages 20658-20668
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 32, 10 August 2017, Pages 20658-20668
نویسندگان
Haili Gao, Shijun Liao, Yong Zhang, Lizhen Wang, Linsen Zhang,