کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5147236 | 1497378 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of low pressure hydrogen environment on crystallographic properties of PdO nanoparticles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effect of low pressure hydrogen environment on crystallographic properties of PdO nanoparticles Effect of low pressure hydrogen environment on crystallographic properties of PdO nanoparticles](/preview/png/5147236.png)
چکیده انگلیسی
Palladium oxide (PdO) nanoparticles (â¼20-130 nm) are synthesized using sol-gel method. The crystal structure of PdO is determined using X-ray diffraction (XRD) whereas surface morphology, shape and size of PdO nanoparticles are analyzed using scanning electron microscopy and transmission electron microscopy. The optical band gap is estimated as 1.8 eV using UV-Vis spectroscopy. The effect of hydrogen gas at low pressure (25, 50, 75 and 100 mbar) on palladium oxide nanoparticle is studied using In-situ X-ray diffraction at room temperature. It is found that face centered cubic (fcc) palladium hydride (PdHx) crystal structure is formed and the intensity of peaks representing tetragonal PdO (t-PdO) crystal structure almost vanished as the pressure increased to 100 mbar. Also, it is found that the value of lattice constant increased significantly, when the pressure becomes equivalent to 100 mbar due to phase transition (α-β) in PdHx lattice. It shows that PdO nanoparticles can be used for storage and sensing of hydrogen gas at ambient atmosphere.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 47, 21 December 2016, Pages 22155-22161
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 47, 21 December 2016, Pages 22155-22161
نویسندگان
Kamal Arora, Deepika Sandil, Gaurav Sharma, Saurabh Srivastava, Nitin K. Puri,