کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5147446 | 1497382 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Efficient CO2-regeneration of Ni/Y2O3La2O3ZrO2 systems used in the ethanol steam reforming for hydrogen production
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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![عکس صفحه اول مقاله: Efficient CO2-regeneration of Ni/Y2O3La2O3ZrO2 systems used in the ethanol steam reforming for hydrogen production Efficient CO2-regeneration of Ni/Y2O3La2O3ZrO2 systems used in the ethanol steam reforming for hydrogen production](/preview/png/5147446.png)
چکیده انگلیسی
This paper reports the study of substoichiometric ethanol steam reforming (ESR) (H2O/ethanol = 1.6 mol ratio) for hydrogen production over new Ni/Y2O3La2O3ZrO2 catalysts. ZrO2-based supports containing Y2O3 and/or La2O3 were prepared by precipitation using active carbon as the templating agent and the Ni-catalysts were then prepared by impregnation. CO2 was used as regenerating agent and its effect was analysed as a function of the characteristics of the catalysts. The CO2 treatment proved to be a powerful tool for regenerating deactivated Ni catalysts through mild oxidation of carbon deposits; this phenomenon is related to the basic characteristics of the catalysts. For Ni/12Zr29Y13La, a high H2 yield and the smallest amount of poorly ordered carbon deposits were determined; full ethanol conversion was achieved during the last 50 h of a long-term (280 h) experiment with periodic CO2 treatments.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 43, 16 November 2016, Pages 19509-19517
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 43, 16 November 2016, Pages 19509-19517
نویسندگان
Lukasz Bednarczuk, Pilar RamÃrez de la Piscina, NarcÃs Homs,