کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5147797 | 1497360 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of proton exchange poly (phenylenebenzophenone)s membranes grafted with propane sulfonic acid on pendant phenyl groups
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of poly(phenylenebenzophenone)s with sulfonic acid groups via long alkyl side chains, SPPBPs, were successfully prepared as proton exchange membranes for fuel cells. The new monomer, 1,4-dichloro-2,5 diphenylenemethoxybenzophenone (PMBP) was synthesized by the Friedel-Crafts reaction of tetrachloroterephthalate with anisole and copolymerized with 1,4-dichloro-2,5-diphenylenebenzophenone (PBP) to prepare poly(phenylenebenzophenone)s copolymers containing dimethoxy groups (sPPMBP). After converting the methoxy group to the reactive hydroxyl group, the resulting side-chain-type sulfonated copolymers (SPPBP) were obtained by a sulfopropylation reaction. These SPPBP series membranes showed high proton conductivity in the range of 98.4-162.1 mS/cm 80 °C under 90% hydrated conditions. SPPBP-40 (IEC = 2.45 meq./g) showed comparable higher proton conductivity (162.1 mS/cm) than Nafion 211 (130.2 mS/cm) in the 90% hydrated state. The membranes were studied by 1H NMR spectroscopy, thermo-gravimetric analysis, ionic exchange capacity, water uptake, and proton conductivity. Also surface morphologies were assessed by atomic force microscope (AFM).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 17, 27 April 2017, Pages 12749-12758
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 17, 27 April 2017, Pages 12749-12758
نویسندگان
Sabuj Chandra Sutradhar, Hohyoun Jang, Nipa Banik, Jiho Yoo, Taewook Ryu, Hanmo Yang, Sujin Yoon, Whangi Kim,