کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5147915 | 1497362 | 2017 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Investigation of V-doped TiO2 as an anodic catalyst support for SPE water electrolysis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A modified evaporation-induced self-assembly (EISA) method was employed to prepare titania samples doped with different amounts of vanadium (0, 10, 20, 30Â at.%), which were further evaluated as catalyst supports for the oxygen evolution reaction (OER) catalyst IrO2 in the solid polymer electrolyte water electrolyzer (SPEWE). The effects of V dopant on titania supports are proved to be twofold: i) enhancing the simplification of phase composition and consequently improving the homogeneity of porous morphology; ii) introducing redox couple V (IV)/V (V) to the surface of titania. As a result, the catalyst's OER activity is improved with the increase of V dopant in the titania support after loading IrO2 via Adams fusion method. In single cells, the OER performance gradually increases with V dopant from 0 to 20Â at.%, followed by a performance deterioration with V amount reaching 30Â at.% due to the corrodible V2O5 precipitate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 15, 13 April 2017, Pages 9384-9395
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 15, 13 April 2017, Pages 9384-9395
نویسندگان
Chuanpu Hao, Hong Lv, Qiang Zhao, Bing Li, Cunman Zhang, Cangen Mi, Yukun Song, Jianxin Ma,