کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5148306 1497365 2017 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Efficient CO2 electrolysis with scandium doped titanate cathode
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Efficient CO2 electrolysis with scandium doped titanate cathode
چکیده انگلیسی
Perovskite oxide (La,Sr)TiO3+δ (LSTO) cathode has demonstrated promising performance for direct CO2 electrolysis due to its unique redox-stable properties. However, insufficient electro-catalytic activity of titanate remains a major drawback that limits electrode performance. In this paper, catalytically active scandium is doped to LSTO to enhance cathode performances. The structure, electronic conductivity and ionic conductivity of La0.2Sr0.8Ti1−xScxO3+δ (LSTSxO) (x = 0, 0.05 and 0.1) are investigated and further correlated with electrode performances. XRD, TEM, TGA and XPS indicate the successful partial replacement of Ti by Sc in the B site of titanate. The improved electrode performances are strongly dependent on scandium doping contents. Promising direct CO2 electrolysis performance is demonstrated with near 100% current efficiency based on La0.2Sr0.8Ti0.9Sc0.1O3+δ at 1.7 V and 800 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 12, 23 March 2017, Pages 8197-8206
نویسندگان
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