کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5148695 1497868 2017 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
In operando infrared spectroscopy of lithium polysulfides using a novel spectro-electrochemical cell
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
In operando infrared spectroscopy of lithium polysulfides using a novel spectro-electrochemical cell
چکیده انگلیسی
A new in operando spectro-electrochemical Li-S cell has been demonstrated. The novel design allows investigations of the liquid electrolyte phase, in a commercial coin cell geometry, at C rates much higher than conventional in situ cells. We use ATR FT-IR spectroscopy, coupled with a previously developed polysulfide diagnostic to quantify the evolution of lithium polysulfides during the discharge and charge cycles of a Li-S cell. The trends observed in the polysulfide order and concentration with respect to state of charge are consistent with prevailing understanding of the electrochemical mechanisms of Li-S battery operation. During discharge, we observe the reduction of elemental sulfur to dissolved Li2S8 polysulfides, and their cascading conversion to smaller polysulfides until insoluble species (Li2S2 and Li2S) are formed. During cell charging, we observe the oxidation of insoluble polysulfides to larger, soluble polysulfides (Li2Sn, n>3), and infer an eventual recovery of crystalline sulfur, from changes in polysulfides. Long-term evolution of polysulfides is observed over 7 discharge/charge cycles. Capacity fading is evident in the decay of polysulfide order and concentration at the same state of charge between cycles. Sulfur is not recovered by charging the cell in the latter cycles, and the active material is lost as solid Li2S.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 364, 1 October 2017, Pages 266-271
نویسندگان
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