کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5149627 | 1497890 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Lithium plating in lithium-ion batteries investigated by voltage relaxation and in situ neutron diffraction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, lithium plating is investigated by means of voltage relaxation and in situ neutron diffraction in commercial lithium-ion batteries. We can directly correlate the voltage curve after the lithium plating with the ongoing phase transformation from LiC12 to LiC6 according to the neutron diffraction data during the relaxation. Above a threshold current of C/2 at a temperature of â2 °C, lithium plating increases dramatically. The results indicate that the intercalation rate of deposited lithium seems to be constant, independent of the deposited amount. It can be observed that the amount of plating correlates with the charging rate, whereas a charging current of C/2 leads to a deposited amount of lithium of 5.5% of the charge capacity and a current of 1C to 9.0%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 342, 28 February 2017, Pages 17-23
Journal: Journal of Power Sources - Volume 342, 28 February 2017, Pages 17-23
نویسندگان
Christian von Lüders, Veronika Zinth, Simon V. Erhard, Patrick J. Osswald, Michael Hofmann, Ralph Gilles, Andreas Jossen,