کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5152406 | 1499412 | 2017 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Impact of the corrin framework of vitamin B12 on the electrochemical carbon-skeleton rearrangement in comparison to an imine/oxime planar ligand; tuning selectivity in 1,2-migration of a functional group by controlling electrolysis potential
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Impact of the corrin framework of vitamin B12 on the electrochemical carbon-skeleton rearrangement in comparison to an imine/oxime planar ligand; tuning selectivity in 1,2-migration of a functional group by controlling electrolysis potential Impact of the corrin framework of vitamin B12 on the electrochemical carbon-skeleton rearrangement in comparison to an imine/oxime planar ligand; tuning selectivity in 1,2-migration of a functional group by controlling electrolysis potential](/preview/png/5152406.png)
چکیده انگلیسی
To probe the mechanism of a model reaction for an enzymatic carbon-skeleton rearrangement, an alkyl bromide substrate having two different migrating groups on the β-carbon (phenyl and carboxylic ester groups) was applied to electrolysis mediated by a hydrophobic B12 model complex in this study.156
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Inorganic Biochemistry - Volume 175, October 2017, Pages 239-243
Journal: Journal of Inorganic Biochemistry - Volume 175, October 2017, Pages 239-243
نویسندگان
Keishiro Tahara, Ling Pan, Ryoko Yamaguchi, Hisashi Shimakoshi, Masaaki Abe, Yoshio Hisaeda,