کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5153116 | 1499813 | 2017 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reactions of palladium(0) olefin complexes stabilized by some different hetero- and homo-ditopic spectator ligands with propargyl halides
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Reactions of palladium(0) olefin complexes stabilized by some different hetero- and homo-ditopic spectator ligands with propargyl halides Reactions of palladium(0) olefin complexes stabilized by some different hetero- and homo-ditopic spectator ligands with propargyl halides](/preview/png/5153116.png)
چکیده انگلیسی
We have studied the reaction between palladium(0) olefin complexes with 3âchloroâ1âpropyne or 3âchloroâ1âphenylâ1âpropyne. In the case of the reaction with 3âchloroâ1âpropyne we have obtained the palladium allenyl derivative only, whereas the oxidative addition of 3âchloroâ1âphenylâ1âpropyne yields a mixture of the allenyl and propargyl tautomers. On the basis of a detailed kinetic study we have hypothesized a mechanism network which in one case was completely disentangled.201
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 834, 15 April 2017, Pages 10-21
Journal: Journal of Organometallic Chemistry - Volume 834, 15 April 2017, Pages 10-21
نویسندگان
Luciano Canovese, Thomas Scattolin, Fabiano Visentin, Claudio Santo,