کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
51555 46847 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
One-pot synthesis of calcium-incorporated MCM-41 as a solid base catalyst for transesterification of palm olein
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
One-pot synthesis of calcium-incorporated MCM-41 as a solid base catalyst for transesterification of palm olein
چکیده انگلیسی

Direct generation of basic sites on mesoporous silica MCM-41 through calcium incorporation was achieved via a one-pot synthesis. The effect of calcium salt precursors was addressed in terms of structure, morphology, and basic property. The catalysts were evaluated for potential application in transesterification of palm olein with methanol to produce biodiesel. Among all of the catalysts tested in this study, the most efficient calcium-incorporated MCM-41 was derived from CaO precursor, affording over 90 wt.% of fatty acid methyl ester after 3 h of reaction at 200 °C.

Figure optionsDownload as PowerPoint slideHighlights
► Calcium-incorporated MCM-41 catalysts were prepared via a one-pot synthesis.
► The catalysts possess ordered mesopores with high surface area.
► The basicity of the catalysts was higher than that of siliceous MCM-41.
► The Ca/MCM-41 catalysts were active for transesterification of vegetable oil.
► The catalysts yielded over 90% biodiesel product.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 16, Issue 1, 30 November 2011, Pages 25–29
نویسندگان
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