کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5156499 | 1500581 | 2017 | 33 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A crosslinked β-cyclodextrin polymer used for rapid removal of a broad-spectrum of organic micropollutants from water
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کلمات کلیدی
Toluene (PubChem CID: 1140)Propranolol hydrochloride (PubChem CID: 62882)β-cyclodextrin (PubChem CID: 444041) - β-سیکلوکودکسترون (PubChem CID: 444041)Adsorption - جذبRapid removal - حذف سریعHigh adsorption capacity - ظرفیت جذب بالاOrganic micropollutants - میکروپولنتن های آلیβ-Cyclodextrin polymer - پلیمر β-Cyclodextrin
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Organic micropollutants in aquatic environment such as plasticizer, pesticide and pharmaceuticals, have posed a serious threat to human health and are emerging as a great challenge to humanity. Traditional water treatment techniques fail to achieve high removal efficiency for low concentration of organic micropollutants. Here we demonstrate a water-insoluble crosslinked β-cyclodextrin (β-CD) polymer able to remove a broad-spectrum of organic micropollutants from water by rapid adsorption. A family of β-CD polymers (β-CDPs) were synthesized by nucleophilic aromatic substitution of β-CD hydroxyl groups and 4,4â²-difluorodiphenylsulfone. The β-CDPs were used to adsorb various organic micropollutants in water by static or dynamic adsorption process. It was found that more than 99% micropollutants in water were removed by flowing the feed water through the column of β-CDPs. The results of static adsorption experiments indicated the adsorption process was fast and the adsorption capacity was very high (the maximal value was 113.0 mg of bisphenol A per gram of β-CDP). The adsorption process was fitted well with the quasi-second-order kinetics and the Langmuir isothermal adsorption model, suggesting that it is mainly a chemical adsorption of monolayer. The water-insoluble characteristic of the β-CDPs is convenient for their separation from the treated solution after adsorption saturation for regeneration and reuse. The adsorption ability of β-CDPs was kept nearly unchanged after five filtration-regeneration cycles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 177, 1 December 2017, Pages 224-231
Journal: Carbohydrate Polymers - Volume 177, 1 December 2017, Pages 224-231
نویسندگان
Zhanghui Wang, Peibin Zhang, Fan Hu, Yifan Zhao, Liping Zhu,