کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5157779 1500599 2017 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Self-assembly of acetylated dextran with various acetylation degrees in aqueous solutions: Studied by light scattering
ترجمه فارسی عنوان
خودمراقبتی از دکستران آستیل شده با درجه استیلیت مختلف در محلول های آبی: با پراکندگی نور مطالعه می شود
کلمات کلیدی
دکستران، فرایند استیل شدن، خودمجموعه، خواص راه حل، پراکندگی نور،
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی
Self-assembly of acetylated dextran (Ac-DEXs) was investigated with a modified dextran with acetic anhydride in the presence of pyridine. The effect of acetylation degree on solution properties has been investigated by static and dynamic light scattering (DLS). Molecular weight (Mw) and the radius of gyration (Rg) of dextran significantly increased with acetylation degree due to the aggregates formation. However, those aggregates noticeably reduced with further increase of acetylation degree. It suggested that the aggregates have shrinkage. The aggregate formation is clearly confirmed by DLS analysis in the presence of the bimodal relaxation distribution for Ac-DEXs. The hydrodynamic radius (Rh) of fast and slow mode is distinctly corresponded with single dextran macromolecules and aggregates, respectively. The Rh of aggregates varied slightly with increasing acetylation degree. The aggregates of Ac-DEXs represent hard spherical nanoparticles whereas the random coil structure is found in dextran. Formation of gel nanoparticles was monitored at the highest acetylated substitution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 159, 1 March 2017, Pages 171-177
نویسندگان
, , , , ,