کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51643 | 46849 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reusable chiral bis(oxazoline)–copper complexes immobilized by donor–acceptor interactions on insoluble organic supports
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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![عکس صفحه اول مقاله: Reusable chiral bis(oxazoline)–copper complexes immobilized by donor–acceptor interactions on insoluble organic supports Reusable chiral bis(oxazoline)–copper complexes immobilized by donor–acceptor interactions on insoluble organic supports](/preview/png/51643.png)
چکیده انگلیسی
Heterogeneous asymmetric Diels–Alder reactions between cyclopentadiene and 3-but-2-enoyl-oxazolidin-2-one were efficiently promoted by reusable chiral bis(oxazoline)–copper catalysts, immobilized through charge transfer interactions with trinitrofluorenone, that was covalently grafted on Merrifield resins. The modified support was also used for the synthesis of both enantiomers of the target product, thanks to the non-covalent anchoring of the catalyst that allowed its easy removal and exchange.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 11, Issue 5, 25 January 2010, Pages 351–355
Journal: Catalysis Communications - Volume 11, Issue 5, 25 January 2010, Pages 351–355
نویسندگان
Guillaume Chollet, Dorian Didier, Emmanuelle Schulz,