کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5177826 1502480 2017 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Optically transparent poly(methyl methacrylate) with largely enhanced mechanical and shape memory properties via in-situ formation of polylactide stereocomplex in the matrix
ترجمه فارسی عنوان
پلی اتیلن شفاف (متیل متاکریلات) با خواص حافظه مکانیکی و شکل به شدت افزایش یافته است از طریق تشکیل موضع استریو کامپلکس پلی¬اکتیو در ماتریکس
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی


- The in-situ formation of polylactide stereocomplex crystallites (sc-PLA) in the PMMA matrix has been achieved by simple melt-blending.
- The morphology and dispersion of sc-PLA micro-particles have been systematically studied.
- The sc-PLA micro-particles could largely enhance the mechanical property and shape memory performance of PMMA without the sacrifice of its excellent optical transparency.

Optically transparent poly(methyl methacrylate) (PMMA)-based blends with significantly enhanced mechanical and shape memory properties have been successfully prepared via in-situ formation of micro-scale polylactide stereocomplex crystallites (sc-PLA) in the PMMA matrix in this work. To achieve this goal, a certain content of poly(l-lactide) (PLLA) was firstly melt-blended with PMMA to obtain completely miscible PMMA/PLLA blends, and then an equimolar poly(d-lactide) (PDLA) was incorporated into the blends, giving rise to the in-situ formation of sc-PLA between PLLA and PDLA. In this way, the micro-scale sc-PLA particles were successfully fabricated and homogeneously dispersed in the PMMA matrix. Consequently, these resultant PMMA/sc-PLA blends possess extremely superior optical transparency, even when the content of sc-PLA reaches up to 12 wt%. A further increase in the content of sc-PLA would lead to the formation of sc-PLA network and aggregation, resulting in the deterioration of optical transparency. Moreover, the incorporation of sc-PLA micro-particles significantly enhances the mechanical property of PMMA and the maximum (≈103 MPa) of these blends demonstrates 50% increase than that (≈70 MPa) of PMMA. More importantly, it has been found that the shape recovery performance of PMMA could be effectively improved by the incorporation of sc-PLA. The optimal shape recovery ratio (86%) and high shape fixing ratio (almost 100%) can be obtained for the PMMA/sc12 blend which exhibits excellent optical transparency. It is reasonable to believe that these optically transparent blends with largely enhanced mechanical and shape memory properties possess great application potential in advanced shape memory fields.

Optically transparent poly(methyl methacrylate) (PMMA)-based blends with significantly enhanced mechanical and shape memory properties have been successfully prepared via in-situ formation of micro-scale polylactide stereocomplex crystallites in the PMMA matrix in this work.278

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 126, 22 September 2017, Pages 231-239
نویسندگان
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