کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5178238 | 1502495 | 2017 | 10 صفحه PDF | دانلود رایگان |
- The sintering process of UHMWPE permit the prelocalization of CNTs in the interfacial region.
- The prelocalization of CNTs in the sintered nanocomposite allows to reach an extremely low electrical percolation threshold.
- An analysis highlights the influence of CNTs prelocalization on the mechanical properties of the nanocomposite.
- The CNTs nucleating effect is significant on the strain-induced crystallization of the nanocomposite in the molten state.
Nascent powder particles of Ultra High Molecular Weight Polyethylene have been covered by multi-walled carbon nanotubes and then processed by means of sintering. The prelocalization of carbon nanotubes in the interfacial region between powder particles of UHMWPE allowed reaching an electrical percolation threshold as low as 0.04Â wt%. It is also a possible way to reinforce specifically the interfacial regions with a very small amount of fillers. Indeed, the nucleation effect of the nanotubes is very strong on the strain-induced crystallization in the melting state of the composite. The tensile experiments above the melting point allowed by the extremely broad rubbery plateau of the UHMWPE show a significant increase in strain-hardening due to the addition of CNTs from 0.02Â wt%. In the solid state the elastic properties, such as yield stress, and the crystallinity can also be increased for higher CNT concentrations despite the presence of aggregates which reduce the elongation at break.
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Journal: Polymer - Volume 111, 24 February 2017, Pages 204-213