کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5178533 | 1502497 | 2017 | 12 صفحه PDF | دانلود رایگان |
- (2-Ethylhexyl) phthalate esters are synthesized with ester or ether alkyne linkages.
- These derivatized alkyne phthalates react with a simple secondary azide model.
- Phthalates are attached to azidized PVC by thermal or Cu catalyzed cycloaddition.
- The rotationally free ether is a better internal plasticizer by Tg than the ester.
Plasticization of PVC was carried out by covalently linking phthalate derivatives via copper-free (thermal) or copper catalyzed azide-alkyne cycloadditions. Di(2-ethylhexyl) phthalate derivatives (DEHP-ether and DEHP-ester) were synthesized and appended to PVC at two different densities. The glass transition temperatures of the modified PVC decreased with increasing content of plasticizer. PVC-DEHP-ether gave lower glass transition temperatures than PVC-DEHP-ester, reflecting the enhanced flexibility of the ether versus ester linker.
196
Journal: Polymer - Volume 109, 27 January 2017, Pages 1-12